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Old May 15th 2009, 01:36 PM   #1
Sodapop
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Chemistry tutorials & FAQs!

Introduction
Chemistry is the science branch that studies the structure, the composition and the properties of matter. It also studies the properties of the chemical reactions: the mixture of certain chemical substances and their results. Chemical reaction can be provoked by human, yes, but they can also happen naturally. Two types of reaction exists: the organic and the inorganic reactions. Organic reactions involve organic compounds such as methane.

Example of a well-known chemical reaction (water):
2H2 + O2 → 2H2O

Energy
is needed during any chemical reaction. It is needed to break the chemical bonds in the substances. When the new bonds are formed, the energy is released. By comparing the chemical energy of the original substances with the chemical energy of the final substances, you can decide if energy is released or absorbed in the overall reaction.

Two branches of chemical reaction exists: the endothermic reactions and the exothermic reactions (endo/exo means inside/outside, thermic means heat). If the reaction is exothermic, heat will be unleashed from the reaction, which will cause nearby heat around the chemical matter. If, on the other hand, it is endothermic, the matter itself will gain heat.

Example of a well-known exothermic reaction:
The reaction between gasoline and oxygen in a car's inner engine.

Important definitions:
Element
► Matter composed of atoms.
Atom
► The smallest particle of an element. It envelopes a positively charged nucleus that is surrounded by electrons.
Electron
► Particle charged negatively (-1) and is 1/1836th the size of a proton. They are outside the atom and in constant motion around it. Chemical reaction are, grosso modo, an exchange of electrons.
Proton
► Particle in the nucleus with a positive charge (+1).
Neutron

► A non-charged particle in the nucleus with the same mass of a proton.

Some useful references:

Unit conversion calculator: http://www.chemicool.com/cgi-bin/unit.pl
Basic graphs: http://www.chemicool.com/graph.html

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Old May 23rd 2009, 04:57 PM   #2
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I. Ideal gas law explanation
Three important factors influence the state of a gas: its pressure, its volume and its temperature. This law is a good approximation to the many possible behaviors of gases under certain restricted conditions. The form of the equation is the following:

pV = nRT
p = pressure of the gas
V = volume of the gas
n = amount of substance (most of the time expressed in moles)
R = ideal gas constant (0.08206 L atm mol^(-1) K^(-1))
T = absolute temperature (usually in Kelvin, where 273 K = 0°C)

As we all know, a formula has to posses the basic equilibrium found in any equality. In this case, the pressure of the gas multiplied by the volume of the gas gives us the numbers of moles multiplied by the constant R and the temperature. Simple algebra can be used to find the unknown or missing variable in our equation.

Please note: Always remember to convert your volume into L (litres), your temperature into K (Kelvin) and your atomspherical pressure into atmospheres (atm). Altough it is possible to solve with kPa units, this reduced form remains the simpliest and the easiest to use. Here is an example:

What is the volume (in L) of 1 mole of an ideal gas at standard temperature (273 K) and at a pressure of 1 atm?

pV = nRT

V = nRT / P

V = (1mol x 0.08206 L atm mol^(-1) K^(-1) x 273K) / 1 atm

Canceling the atms, we have:

V = (1mol x 0.08206 L mol^(-1) K^(-1) x 273K) / 1

Canceling the mols and the K [(mol^(-1) K^(-1)) x (1mol x 273K)]:

V = (1 x 0.08206 L x 273) / 1

V = (1 x 0.08206 L x 273)

V = (0.08206 L x 273)

V = 22.4 L

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Old May 23rd 2009, 05:10 PM   #3
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II. Lewis structure
The Lewis structure represents, in a small scheme, the total number of valence electrons by adding small dots around the element symbol. Non-valence electrons are not represented in this structure. The octet rule says that molecules with eight electrons on their valence shell (last shell) will acquire stability.

Once the total number of available electrons has been determined, electrons must be placed into the structure. They should be placed initially as lone pairs: one pair of dots for each pair of electrons available. Lone pairs should initially be placed on outer atoms (other than hydrogen) until each outer atom has eight electrons in bonding pairs and lone pairs; extra lone pairs may then be placed on the central atom. When in doubt, lone pairs should be placed on more electronegative atoms first.

Advanced studies of the Lewis structure lets us place and study the bonds between the molecules.

The Lewis structure for the Neon molecule is the following:

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Old Jun 19th 2009, 08:03 AM   #4
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III. Periodic table
The groups are the vertical columns found in the periodic table. They are the most important classification of the periodic table: properties of elements in a same group usually share similarities.

* Group 1 (IA,IA): the alkali metals or lithium family
* Group 2 (IIA,IIA): the alkaline earth metals or beryllium family
* Group 3 (IIIA,IIIB): the scandium family
* Group 4 (IVA,IVB): the titanium family
* Group 5 (VA,VB): the vanadium family
* Group 6 (VIA,VIB): the chromium family
* Group 7 (VIIA,VIIB): the manganese family
* Group 8 (VIII, VIIIB): the iron family
* Group 9 (VIII, VIIIB): the cobalt family
* Group 10 (VIII, VIIIB): the nickel family
* Group 11 (IB,IB): the coinage metals or copper family
* Group 12 (IIB,IIB): the zinc family
* Group 13 (IIIB,IIIA): the boron family
* Group 14 (IVB,IVA): the carbon family
* Group 15 (VB,VA): the pnictogens or nitrogen family
* Group 16 (VIB,VIA): the chalcogens or oxygen family
* Group 17 (VIIB,VIIA): the halogens or fluorine family
* Group 18 (Group 0): the helium family/neon family; for the first six periods, these are the noble gases

The periods are the horizontal rows of the periodic table. Although they have no specific names, they are also used for classification in the periodic table. Two elements facing each other in the same period have ±1 number of protons. There is a total of seven periods, excluding the Lanthanide series and the Actinide series.



*CURRENT ATTACHED IMAGE IS NOT WORKING. IT WILL BE UPDATED SOON.

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Old Jun 21st 2009, 11:06 AM   #5
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IV. Potential of Hydrogen (pH)
The pH is the measurement of basicity/acidity in a solution. The following scale represents the different values and gives us common examples:

Solutions with a pH under 7 are said to be acid while solution with a pH over 7 are said to be basic. A basic solution can be as dangerous if not more than an acid solution. Also, take note that the temperature of a solution also slightly affects its pH.

When an acid gets dissolved into water, the pH of the solution drops under 7, depending on the pH of the used acid. Stronger acids drops the pH more quickly, while stronger bases raises the pH more quickly. That's where the concept of neutralization takes life: you need a strong base to neutralize (bring back to a pH of 7) a strong acid. When a solution is successfully neutralized, it creates water (H20) and salt (NaCl). The balanced equation of a neutralization is the following:
HCl [acid] + Na(OH) [base] -> H2O [water] + NaCl [salt].

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Old Dec 7th 2009, 02:35 AM   #6
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Interactive chemistry site

Hello everybody!
I launched a new chemistry site to help students. You can download the study material from this site freely.
http://www.adichemadi.com

Aditya
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Old Jan 2nd 2010, 02:30 AM   #7
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Post Useful Links

Here is a list of useful websites for chemists and students of chemistry. If anyone has any other suggestions, feel free to post them in a response to this thread.

www.chemicalregister.com

http://webbook.nist.gov/chemistry
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Old Jan 14th 2010, 07:35 AM   #8
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Thumbs up

http://www.chembuddy.com/

for chromatographers

http://www.lcresources.com/resources/TSWiz/
__________________
Handy Guide to Modern Science:
  • 1. If it's green or it wiggles, it's biology.
    2. If it stinks, it's chemistry.
    3. If it doesn't work, it's physics.
    4. If it's incomprehensible, it's mathematics.
    5. If it doesn't make sense, it's either economics or psychology.
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Old Jan 15th 2010, 08:27 PM   #9
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Send a private message if you have any requests. If you want to write your own tutorials about anything not listed above, your help would be greatly appreciated! I'll make sure to delete the non-relevant posts of this thread, let's keep this clean but active!

This post will be deleted and replaced as the last post of this thread every time something new is added. Like this, we will keep you notified. Thanks!
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Old Mar 5th 2013, 10:46 AM   #10
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hey guys!
im creating a series of videos for high school students to help them understand chemistry in a fun way!Just released the second video : http://www.youtube.com/watch?v=_rewQ28RTHU

Feel free to leave suggestions and tell me how i'm doing
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Old Mar 2nd 2014, 03:37 PM   #11
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Grade 12 chemistry question

Hello,

I need help with the following question:

Write a procedure that would follow to demonstrate the effect of increasingly higher concentrations of hydrochloric acid on its rate of reaction with antacid tablets. Can only use materials listed:
- Hydrochloric acid (with a concentration of 1.0 mol/L)
- Distilled water
- Antacid tablets (calcium carbonate)
- A mortar and pestle
- Graduated cylinders (10 mL, 100 mL sizes)
- Test tubes and beakers
- Balance and measuring pan
- Hot plate (heat source)
- Thermometer
- Stopwatch or other timing device
- Ice-water bath
- Scoop

I realize that hydrochloric acid needs to be diluted with water in 4 beakers. Each beaker will contain different amount of HCL in it. Im having a hard with starting the procedure please assist.

Thanks
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Old Sep 9th 2014, 10:33 AM   #12
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Here is another wonderful chemistry website containing 50 calculators and unit converters etc.

http://calistry.org

here are some calculators, have a look and please give your suggestions

1. Balancing Chemical Equations : This is chemical equation balancer , it can be used for chemical equations like "NaOH + H2SO4 = Na2SO4 + H2O".
visit: http://calistry.org/calculate/balanceChemicalEquation
2. Molecular Weight Calculator : Also displays a cool Pie chart on the % weight contribution of different elements. Amino acid sequences are also supported (eg. ProValGlyTyr )
visit: http://calistry.org/molecular-Weight-Calculate

3. Effective Nuclear Charge Calculator: This based on the Slater's rule:
visit: http://calistry.org/calculate/slaterRuleCalculator
4. Van Der Waals equation calculator: http://calistry.org/calculate/vanDerWaalsCalculator
5. Gay Lussac Calculator: http://calistry.org/calculate/gayLussacsLawCalculator
6. Wave length visualizer : http://calistry.org/wavelengthVisibleSpectrum


Here
there are 50 more in the site

Last edited by arkajit; Sep 9th 2014 at 10:59 AM.
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